(Cycloheptatrienyl)(cyclopentadienyl)vanadium is an organovanadium compound with the formula V(C5H5)(C7H7). It is a purple, paramagnetic, sublimable solid that is sensitive toward air. The structure has been confirmed by X-ray crystallography. This sandwich complex features cyclopentadienyl and cycloheptatrienyl ligands bound to vanadium. It was first prepared by heating a mixture of cycloheptatriene and cyclopentadienylvanadium tetracarbonyl. Many derivatives of trovacene are prepared by lithiation of the cyclopentadienyl ring.

See also

  • (Cycloheptatrienyl)(cyclopentadienyl)titanium

References


Cyclopentadien1,2,3,4,5pentacarbonsäurepentamethylester 97 16691591

TRANSITION METAL COMPLEXES OF CYCLOPENTADIENYL FUSED HETROCYCLES.pptx

Bis(cyclopentadienyl)vanadium chloride C10H10Cl2V2 CID 82917 PubChem

Cyclopentadienyl

Cyclopentadien (Strukturformel) DocCheck